Long-lived platinum(II) diimine complexes with broadband excited-state absorption: efficient nonlinear absorbing materials.
نویسندگان
چکیده
Platinum(II) diimine complexes with naphthalimide substituted fluorenylacetylide ligands are synthesized and characterized. The complexes exhibit long-lived (3)ILCT or (3)ILCT/(3)MLCT/(3)LLCT excited states (τ = ~20-30 μs) and broadband triplet transient absorption in the visible-NIR region. Nonlinear transmission experiments at 532 nm demonstrate that these complexes are efficient nonlinear absorbing materials.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 40 شماره
صفحات -
تاریخ انتشار 2012